There are clearly specific sequence/steps to use Chrome extension with multiple personas. They are spread over many forum posts. Many of the posts are out of date. Could an expert update the steps.
My specific experience:
New Install. Specifically local data was empty. Fresh login.
Install Chrome extension under Work User.
The 1password extension never worked. Clicking on the icon produced nothing.
Chrome Version 58.0.3029.110 (64-bit).
No problems in Firefox.
1Password Version: 6
Extension Version: chrome
OS Version: Windows 10
Sync Type: Not Provided