Might be missing something here . . .
Using Wi-Fi sync, but don't see a quick sync option, whether manual or automatic.
Desktop: Open 1Password, Window, Wi-Fi Sync (could be better, but not too much trouble)
iOS: Open 1Password, press settings, then sync, then wi-fi sync, then computer to sync to, then sync now, wait.
Yikes! Can't there just be a sync button on the main window?